TY - JOUR UR - http://dx.doi.org/10.1063/1.1903923 A1 - Morrison, Greg A1 - Thirumalai, D. JF - Journal of Chemical Physics Y1 - 2005/// PB - American Institute of Physics VL - 122 IS - 19 AV - public SN - 0021-9606 ID - eprints1813 TI - The shape of a flexible polymer in a cylindrical pore N2 - We calculate the mean end-to-end distance R of a self-avoiding polymer encapsulated in an infinitely long cylinder with radius D. A self-consistent perturbation theory is used to calculate R as a function of D for impenetrable hard walls and soft walls. In both cases, R obeys the predicted scaling behavior in the limit of large and small D. The crossover from the three-dimensional behavior (D??) to the fully stretched one-dimensional case (D?0) is nonmonotonic. The minimum value of R is found at D ? 0.46RF, where RF is the Flory radius of R at D??. The results for soft walls map onto the hard wall case with a larger cylinder radius. ER -