@article{eprints2811, pages = {1543--1548}, publisher = {John Wiley \& Sons, Ltd}, year = {2011}, author = {J. N. Li and C. Z. Chen and B. B. Cui and Tiziano Squartini}, journal = {Surface and Interface Analysis}, title = {Surface modification of titanium alloy with the Ti3Al + TiB2/TiN composite coatings}, number = {12}, volume = {43}, url = {http://eprints.imtlucca.it/2811/}, abstract = {Laser cladding of the Ti3Al + TiB2 pre-placed alloy powder on the Ti?6Al?4 V alloy in nitrogen protective atmosphere can form the Ti3Al + TiB2/TiN composite coating, which can dramatically improve the wear resistance of the Ti?6Al?4 V alloy surface. In this study, the Ti3Al + TiB2/TiN composite coatings on the Ti?6Al?4 V alloy have been researched by means of X-ray diffraction, SEM and energy dispersive spectrometry. It was found that there is a metallurgical combination between the Ti3Al + TiB2/TiN composite coating and the substrate. The microhardness of the Ti3Al + TiB2/TiN composite coatings were 3 {\texttt{\char126}} 4 times higher than that of the Ti?6Al?4 V alloy because of the actions of the Ti3Al + TiB2/TiN hard phases and the grain refinement strengthening. Moreover, the wear mass losses of the Ti3Al + TiB2/TiN composite coatings were much lower than that of the substrate. Copyright {\copyright} 2011 John Wiley \& Sons, Ltd.}, keywords = {Laser cladding technology, Interface, surfaces, Composite coating} }