%N 12 %V 43 %X Laser cladding of the Ti3Al + TiB2 pre-placed alloy powder on the Ti?6Al?4 V alloy in nitrogen protective atmosphere can form the Ti3Al + TiB2/TiN composite coating, which can dramatically improve the wear resistance of the Ti?6Al?4 V alloy surface. In this study, the Ti3Al + TiB2/TiN composite coatings on the Ti?6Al?4 V alloy have been researched by means of X-ray diffraction, SEM and energy dispersive spectrometry. It was found that there is a metallurgical combination between the Ti3Al + TiB2/TiN composite coating and the substrate. The microhardness of the Ti3Al + TiB2/TiN composite coatings were 3 ~ 4 times higher than that of the Ti?6Al?4 V alloy because of the actions of the Ti3Al + TiB2/TiN hard phases and the grain refinement strengthening. Moreover, the wear mass losses of the Ti3Al + TiB2/TiN composite coatings were much lower than that of the substrate. Copyright ? 2011 John Wiley & Sons, Ltd. %L eprints2811 %K Laser cladding technology, Interface, surfaces, Composite coating %I John Wiley & Sons, Ltd %D 2011 %A J. N. Li %A C. Z. Chen %A B. B. Cui %A Tiziano Squartini %J Surface and Interface Analysis %P 1543-1548 %R 10.1002/sia.3809 %T Surface modification of titanium alloy with the Ti3Al + TiB2/TiN composite coatings