relation: http://eprints.imtlucca.it/3655/
title: A reaction-diffusion formulation to simulate EVA polymer degradation in environmental and accelerated ageing conditions
creator: Gagliardi, Mariacristina
creator: Lenarda, Pietro
creator: Paggi, Marco
subject: TA Engineering (General). Civil engineering (General)
description: Among polymers used as encapsulant in photovoltaic (PV) modules, poly(ethylene-co-vinyl acetate), or EVA, is the most widely used, for its low cost and acceptable performances. When exposed to weather conditions, EVA undergoes degradation that affects overall PV performances. Durability prediction of EVA, and thus of the module, is a hot topic in PV process industry. To date, the literature lacks of long-term predictive computational models to study EVA aging. To fill this gap, a computational framework, based on the finite element method, is proposed to simulate chemical reactions and diffusion processes occurring in EVA. The developed computational framework is valid in either case of environmental or accelerated aging. The proposed framework enables the identification of a correspondence between induced degradation in accelerated tests and actual exposure in weathering conditions. The developed tool is useful for the prediction of the spatio-temporal evolution of the chemical species in EVA, affecting its optical properties. The obtained predictions, related to degradation kinetics and discoloration, show a very good correlation with experimental data taken from the literature, confirming the validity of the proposed formulation and computational approach. The framework has the potential to provide quantitative comparisons of degradation resulting from any environmental condition to that gained from accelerated aging tests, also providing a guideline to design new testing protocols tailored for specific climatic zones.
publisher: Elsevier
date: 2017
type: Article
type: PeerReviewed
format: application/pdf
language: en
identifier: http://eprints.imtlucca.it/3655/1/1-s2.0-S0927024817300673-main.pdf
identifier:   Gagliardi, Mariacristina and Lenarda, Pietro and Paggi, Marco  A reaction-diffusion formulation to simulate EVA polymer degradation in environmental and accelerated ageing conditions.  Solar Energy Materials and Solar Cells, 164.  pp. 93-106.  ISSN 0927-0248      (2017)  
relation: http://www.sciencedirect.com/science/article/pii/S0927024817300673
relation: 10.1016/j.solmat.2017.02.014